The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Peroxy radicals / Alkylperoxy / CH3O2 / Anastasi(1978)_298K_215-280nm

DATAFILE: CH3O2_Anastasi(1978)_298K_215-280nm.txt
NAME: methylperoxy radical
FORMULA: CH3O2
AUTHOR(YEAR): Anastasi(1978)
T: 298K
λ: 215-280nm
BIBLIOGRAPHY: C. Anastasi, I.W.M. Smith, and D.A. Parkes, "Flash photolysis study of the spectra of CH3O2 and C(CH3)3O2 radicals and the kinetics of their mutual reactions and with NO", J. Chem. Soc. Faraday Trans. I 74, 1693-1701 (1978); DOI: 10.1039/F19787401693
COMMENTS: Absorption cross sections have been derived from the absorbances plotted in Fig. 1 (scaling to σ(225 nm) of Adachi et al. (1980); DOI: 10.1002/kin.550121206 ?) by

P.D. Lightfoot, R.A. Cox, J.N. Crowley, M. Destriau, G.D. Hayman, M.E. Jenkin, G.K. Moortgat, and F. Zabel, "Organic peroxy radicals: Kinetics, spectroscopy and tropospheric chemistry," Atmos. Environ. 26A, 1805-1961 (1992); DOI: 10.1016/0960-1686(92)90423-I

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